Long-term monitoring of carbonate reference standards (ETH-1–4, IAEA-C2, CIT) and external accuracy checks (IAEA-C1, GU-1, MERCK — not used in Δ₄₇ standardization) measured on the Nu Perspective IRMS. Monitored non-anchor standards (dolomite: SANSA, RODOLO, SRM-88B; apatite: RHINO-DENTIN) tracked for reproducibility. Data processed through BLIMP → D47crunch and updated weekly via automated sync. ETH 1-4 and IAEA standard values from Bernasconi et al. (2021, 2018). GU-1 nominal values from Fiebig et al. (2024).
Analyses per Standard
Standard Analyses per Session
Recent Performance Snapshot
Zoomed view of the last 30 days of data to quickly evaluate short-term instrument performance. Flags sessions with elevated scatter or systematic offsets before they accumulate into long-term drift. All plots show the same green/yellow/red bands as the full time series.
Δ₄₇ Residuals — Last 30 Days
δ¹³C Residuals — Last 30 Days
δ¹⁸O Residuals — Last 30 Days
Δ₄₇ Session Strip — Last 30 Days
CUSUM — Last 30 Days (ETH-1/2)
EWMA — Last 30 Days (ETH-1/2)
δ¹³C (VPDB) — All Standards Over Time
δ¹³C Time Series (colored by standard)
δ¹³C Residuals from Nominal
δ¹⁸O — All Standards Over Time
δ¹⁸O Time Series (colored by standard)
δ¹⁸O Residuals from Nominal
Δ₄₇ (I-CDES) — Clumped Standards Over Time
Δ₄₇ Time Series
Δ₄₇ Residuals from Nominal
Δ₄₈ (raw) — Clumped Standards Over Time
Δ₄₈ (raw) Time Series
Δ₄₉ — Clumped Standards Over Time
Δ₄₉ monitors the exclusively ¹³C¹⁸O¹⁸O isotopologue. Together with Δ₄₇ and Δ₄₈, it enables identification of isobaric interferences and provides an additional quality control dimension (Bernecker et al. 2023).
Δ₄₉ Time Series
Δ₄₇ / Δ₄₈ and Δ₄₈ / Δ₄₉ Cross-Plots
Data plotted relative to the equilibrium relationship (Fiebig et al. 2021). Only data from after 31 Oct 2024 (pre-amp bin pump + collector upgrade) is shown. Points deviating from the equilibrium line may indicate kinetic effects, isobaric interferences, or CO₂–H₂O re-equilibration. The NO₂ interference vector is shown in the ETH-3 diagnostics section.
Δ₄₈ vs Δ₄₇ — All Clumped Standards
Δ₄₈ vs Δ₄₉ — All Clumped Standards
Attribution: Session vs Standard Problem?
Session strip plots show per-session deviations of each standard from its long-term mean. Session-wide offsets (all standards shift together) indicate instrument or acid-line issues. Single-standard outliers suggest material degradation or prep problems. The monitored-vs-anchor divergence plot tracks whether non-anchor standards (SANSA, RODOLO, SRM-88B, RHINO-DENTIN) drift independently of anchor standards — a key diagnostic for separating instrument from sample-prep issues.
Δ₄₇ Session Strip — Deviation from Long-Term Mean
Monitored vs Anchor Divergence (Δ₄₇)
Monitored vs Anchor Divergence (δ¹³C)
Monitored vs Anchor Divergence (δ¹⁸O)
Session-Level Standard Deviations
1 SD of each standard within each session, tracked over time. The red rolling line shows the pooled 1SD across a trailing 20-session window — a moving measure of instrument precision. The yellow dashed line marks the August 2023 48-cup collector upgrade. Use the precision window buttons in the Overview to compare long-term vs. recent performance.
δ¹³C 1SD per Session
δ¹⁸O 1SD per Session
Δ₄₇ 1SD per Session
Transducer Pressure Over Time
Unknown Sample → Standard Matching
Standards flagged by post-crunch mislabel detection: analyses where all four standardized values (δ¹³C, δ¹⁸O, δ₄₇, Δ₄₇) convincingly match a different standard's cluster. Confidence is based on max z-score across all four parameters. Review candidates on the plots, then add confirmed UIDs to the Names_to_change sheet in params.xlsx.
Access Full Dataset
Download complete standards QC outputs from the GitHub repository. Updated weekly via automated pipeline.